Activity coefficients and conductances of high-charge (4-1,1-4,1-2) electrolytes. II

被引：18

作者：

Groves, Kenneth O. ^{[1
]}

Dye, Jaiaes L. ^{[1
]}

Brubaker, Carl H., Jr. ^{[1
]}

机构：

[1] Michigan State Univ, Kedzie Chem Lab, E Lansing, MI 48824 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1960年 / 82卷 / 17期

关键词：

D O I：

10.1021/ja01502a002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mean activity and osmotic coefficients of aqueous solutions of Pt(pn)(3)Cl-4, (NMe4](4)MO(CN)(3). K4W(CN)(8) and K2Pt(CN)(4) were determined at 25 degrees by isopiestic comparison with aqueous KCl solutions. The Debye-Huckel equation plus a linear term in concentration fit the data at low concentrations. Conductivity measurements were made with solutions of the four electrolytes and decided deviations from the Onsager limiting law were observed. The behavior of these unsymmetrical electrolytes and relationship to present theory is discussed.

引用

页码：4445 / 4448

页数：4