RESIDENCE TIMES AND COVERAGE BY SURFACE INTERMEDIATES DURING THE FISCHER-TROPSCH SYNTHESIS

被引：33

作者：

MIMS, CA ^{[1
]}

KRAJEWSKI, JJ ^{[1
]}

ROSE, KD ^{[1
]}

MELCHIOR, MT ^{[1
]}

机构：

[1] EXXON RES & ENGN CO, CORP RES LABS, ANNANDALE, NJ 08801 USA

来源：

CATALYSIS LETTERS | 1990年 / 7卷 / 1-4期

关键词：

FISCHER-TROPSCH SYNTHESIS; HYDROCARBON CHAIN GROWTH; SURFACE POLYMERIZATION; FT REACTION MECHANISM; CARBON NUMBER PRODUCT CONCENTRATION; ETHYLENE TRACER; ISOTOPE DISTRIBUTION IN BUTENE; HEXENE TRACER;

D O I：

10.1007/BF00764495

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Isotope tracing of alkene readsorption has been used to examine reversibility in the growth of higher hydrocarbons in the Fischer-Tropsch synthesis. Some reversibility is indicated, but the degree is insufficient to change previous conclusions from isotope transient studies; namely that the surface concentrations of the growing hydrocarbon oligomers during the reaction are very small. © 1991 J.C. Baltzer A.G., Scientific Publishing Company.

引用

页码：119 / 125

页数：7

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