RESIDENCE TIMES AND COVERAGE BY SURFACE INTERMEDIATES DURING THE FISCHER-TROPSCH SYNTHESIS

被引：33

作者：

MIMS, CA ^{[1
]}

KRAJEWSKI, JJ ^{[1
]}

ROSE, KD ^{[1
]}

MELCHIOR, MT ^{[1
]}

机构：

[1] EXXON RES & ENGN CO, CORP RES LABS, ANNANDALE, NJ 08801 USA

来源：

CATALYSIS LETTERS | 1990年 / 7卷 / 1-4期

关键词：

FISCHER-TROPSCH SYNTHESIS; HYDROCARBON CHAIN GROWTH; SURFACE POLYMERIZATION; FT REACTION MECHANISM; CARBON NUMBER PRODUCT CONCENTRATION; ETHYLENE TRACER; ISOTOPE DISTRIBUTION IN BUTENE; HEXENE TRACER;

D O I：

10.1007/BF00764495

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Isotope tracing of alkene readsorption has been used to examine reversibility in the growth of higher hydrocarbons in the Fischer-Tropsch synthesis. Some reversibility is indicated, but the degree is insufficient to change previous conclusions from isotope transient studies; namely that the surface concentrations of the growing hydrocarbon oligomers during the reaction are very small. © 1991 J.C. Baltzer A.G., Scientific Publishing Company.

引用

页码：119 / 125

页数：7

共 14 条

[11] RECENT RESULTS IN SYNTHESIS OF HYDROCARBONS FROM CO AND H2 [J].

PICHLER, H ;

SCHULZ, H .

CHEMIE INGENIEUR TECHNIK, 1970, 42 (18) :1162-&

[12] INFRARED STUDY OF THE REACTION OF H2+CO ON A RU-SIO2 CATALYST [J].

YAMASAKI, H ;

KOBORI, Y ;

NAITO, S ;

ONISHI, T ;

TAMARU, K .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1981, 77 :2913-2925

[13] A TRANSIENT KINETIC OBSERVATION OF CHAIN GROWTH IN THE FISCHER-TROPSCH SYNTHESIS [J].

ZHANG, XH ;

BILOEN, P .

JOURNAL OF CATALYSIS, 1986, 98 (02) :468-476

[14] TRANSIENT FTIR STUDY OF SURFACE ALKYL-GROUPS ON RU/SIO2 [J].

ZHOU, X ;

GULARI, E .

LANGMUIR, 1988, 4 (06) :1332-1340

← 1 2 →