SOME SUBSTITUTION REACTIONS OF NIOBIUM(IV) HALIDES

被引：12

作者：

MACHIN, DJ

SULLIVAN, JF

机构：

[1] Department of Chemistry, The University, Manchester

来源：

JOURNAL OF THE LESS-COMMON METALS | 1969年 / 19卷 / 04期

关键词：

D O I：

10.1016/0022-5088(69)90186-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reactions of niobium(IV) chloride, bromide and iodide with potassium thiocyanate, cyanate, cyanide, and borohydride; sodium diethyldithiocarbamate, and N,N′-bis (salicylidene) ethylenediammine have been investigated. Complete replacement of halide occurs only in the case of the reaction with sodium diethyldithiocarbamate, other reactions leading to complex stoichiometries. The magnetic, and vibrational and electronic spectral properties of the products are described. © 1969.

引用

页码：413 / &

共 28 条

[11] STRUCTURE OF NITROSYLRUTHENIUM TRIS-(NN-DIETHYLDITHIOCARBAMATE) - A COMPLEX WITH A MONODENTATE DITHIOCARBAMATE GROUP [J].

DOMENICANO, A ;

VACIAGO, A ;

ZAMBONEL.L .

CHEMICAL COMMUNICATIONS, 1966, (14) :476-+

[12]

FACKLER JP, 1966, INORG NUCL CHEM LETT, V2, P251, DOI DOI 10.1016/0020-1650(66)80055-7

[13] VIBRATIONAL SPECTRA OF PSEUDOHALIDE COMPLEXES .I. TETRAHEDRAL ISOCYANATE COMPLEXES [J].

FORSTER, D ;

GOODGAME, DM .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (JAN) :262-&

[14] PREPARATION ELECTRONIC SPECTRA + MAGNETIC PROPERTIES OF SOME TRANSITION-METAL ISOCYANATO-COMPLEXES [J].

FORSTER, D ;

GOODGAME, DM .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (AUG) :2790-+

[15]

GUERCHAIS JE, 1964, CR HEBD ACAD SCI, V259, P1135

[16]

JORGENSEN CK, 1962, ABSORPTION SPECTRA C, P196

[17]

KING RB, 1963, Z NATURFORSCH PT B, VB 18, P157

[18]

LAPITSKII AV, 1961, RUSS J INORG CHEM, V6, P333

[19] STRUCTURE OF COMPLEX MOLYBDENUM(III) THIOCYANATES [J].

LEWIS, J ;

SMITH, PW ;

NYHOLM, RS .

JOURNAL OF THE CHEMICAL SOCIETY, 1961, (OCT) :4590-&

[20]

MAKI A, 1958, J CHEM PHYS, V28, P1234

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