HYDROSILYLATION CATALYZED BY ORGANONEODYMIUM COMPLEXES

被引：145

作者：

SAKAKURA, T ^{[1
]}

LAUTENSCHLAGER, HJ ^{[1
]}

TANAKA, M ^{[1
]}

机构：

[1] NATL CHEM LAB IND,TSUKUBA,IBARAKI 305,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 01期

关键词：

D O I：

10.1039/c39910000040

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[(C5Me5)2NdH]2 and (C5Me5)2NdCH(SiMe3)2 effectively catalyse the hydrosilylation of alkenes with di- or tri-hydrosilanes at 30 to 80-degrees-C; the regioselectivity in the reaction of styrene depends to a considerable extent on the substituents of the silanes.

引用

页码：40 / 41

页数：2

共 18 条

[1] NICKEL COMPLEXES AS HYDROSILATION CATALYSTS
BENNETT, EW
ORENSKI, PJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 28 (01) : 137 - &
[2] CAPKA M, 1973, COLLECT CZECH CHEM C, V38, P3830
[3] THE ORGANOMETALLIC CHEMISTRY OF THE LANTHANIDE ELEMENTS IN LOW OXIDATION-STATES
EVANS, WJ
[J]. POLYHEDRON, 1987, 6 (05) : 803 - 835
[4] Fleming I., 1979, COMPREHENSIVE ORGANI, V3, P539
[5] ORGANOLANTHANIDE-CENTERED HYDROAMINATION CYCLIZATION OF AMINOOLEFINS - EXPEDIENT OXIDATIVE ACCESS TO CATALYTIC CYCLES
GAGNE, MR
NOLAN, SP
MARKS, TJ
[J]. ORGANOMETALLICS, 1990, 9 (06) : 1716 - 1718
[6] SILYLTITANOCENE COMPLEXES AS CATALYSTS FOR THE HYDROGENATION, ISOMERIZATION, AND HYDROSILATION OF OLEFINS
HARROD, JF
YUN, SS
[J]. ORGANOMETALLICS, 1987, 6 (07) : 1381 - 1387
[7] ORGANOLANTHANIDE-CATALYZED CYCLODIMERIZATIONS OF DISUBSTITUTED ALKYNES
HEERES, HJ
HEERES, A
TEUBEN, JH
[J]. ORGANOMETALLICS, 1990, 9 (05) : 1508 - 1510
[8] HIGHLY REACTIVE ORGANOLANTHANIDES - A MECHANISTIC STUDY OF CATALYTIC OLEFIN HYDROGENATION BY BIS(PENTAMETHYLCYCLOPENTADIENYL) AND RELATED 4F COMPLEXES
JESKE, G
LAUKE, H
MAUERMANN, H
SCHUMANN, H
MARKS, TJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) : 8111 - 8118
[9] HIGHLY REACTIVE ORGANOLANTHANIDES - SYSTEMATIC ROUTES TO AND OLEFIN CHEMISTRY OF EARLY AND LATE BIS(PENTAMETHYLCYCLOPENTADIENYL) 4F HYDROCARBYL AND HYDRIDE COMPLEXES
JESKE, G
LAUKE, H
MAUERMANN, H
SWEPSTON, PN
SCHUMANN, H
MARKS, TJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) : 8091 - 8103
[10] KOROLEVA GN, 1967, ZH OBSHCH KHIM+, V37, P2774

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