PREPARATION OF 2,5-DISILYLATED THIOPHENE DERIVATIVES AND THEIR CONVERSION TO 2,5-DIHALO DERIVATIVES

被引:36
作者
FURUKAWA, N [1 ]
HOSHIAI, H [1 ]
SHIBUTANI, T [1 ]
HIGAKI, M [1 ]
IWASAKI, F [1 ]
FUJIHARA, H [1 ]
机构
[1] UNIV ELECTROCOMMUN,DEPT APPL PHYS & CHEM,CHOFU KU,CHOFU,TOKYO 182,JAPAN
关键词
D O I
10.3987/COM-92-6015
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
2,5-Disilylated thiophenes were prepared and readily oxidized with m-chloroperbenzoic acid (m-CPBA) to give the corresponding 1,1-dioxides. The thiophene dioxide was converted to 2,5-dihalogenothiophene dioxides with halogenating agents.
引用
收藏
页码:1085 / 1088
页数:4
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