A NEW ROUTE TO 1,3-DIPHOSPHOLIDE IONS - SYNTHESIS AND X-RAY STRUCTURE-ANALYSIS OF A 1,3-DIPHOSPHAFERROCENE

被引：28

作者：

MAIGROT, N ^{[1
]}

RICARD, L ^{[1
]}

CHARRIER, C ^{[1
]}

MATHEY, F ^{[1
]}

机构：

[1] ECOLE POLYTECH,DCPH,CHIM PHOSPHORE & MET TRANSIT LAB,F-91128 PALAISEAU,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 05期

关键词：

D O I：

10.1002/anie.199005341

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New perspectives are opened by the synthesis of 1,3‐diphospholide ions such as 2 from 1,2‐diphosphetenes like 1. The Ph substituents of 2 are easily varied by choosing an appropriately substituted starting material; even the H atom in 2 is subject to replacement. Compound 2 reacts with a cationic cyclopentadienyliron species to give the corresponding terrocene analogue. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：534 / 535

页数：2