WEAK FIELD REPRESENTATION OF CRYSTAL FIELD MATRICES OF D4,6 IONS AND ELECTRONIC ABSORPTION SPECTRUM OF RBFEF3

被引：14

作者：

FERGUSON, J

GUGGENHE.HJ

KRAUSZ, ER

机构：

[1] Division of Applied Physics, National Standards Laboratory, CSIRO, Chippendale, NSW

[2] Bell Telephone Laboratories, Murray Hill, NJ

[3] Department of Physical Chemistry, University of Sydney, NSW

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 09期

关键词：

D O I：

10.1071/CH9691809

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electronic absorption spectrum of RbFeF3 is reported and analysed by means of crystal field theory. It is shown that the strong field formalism is limited for high spin Fe2+ and the weak field representation should be used to interpret the many triplet states. Published spin-orbit weak field matrices for d4,6 are shown to contain errors. The weak field matrices in the absence of spin-orbit coupling have been derived and they are used to assign the spectrum of RbFeF3. © 1969, CSIRO. All rights reserved.

引用

页码：1809 / &

共 19 条

[1]

[Anonymous], SOLID STATE PHYS

[2] MATRIX ELEMENTS FOR CONFIGURATION D4 IN A WEAK OCTAHEDRAL FIELD USING RACAH METHODS [J].