PARTITION-FUNCTION AND FORCE EXTENSION RELATION FOR A GENERALIZED FREELY JOINTED CHAIN

被引：33

作者：

GLATTING, G ^{[1
]}

WINKLER, RG ^{[1
]}

REINEKER, P ^{[1
]}

机构：

[1] UNIV ULM,THEORET PHYS ABT,ALBERT EINSTEIN ALLEE 11,D-89081 ULM,GERMANY

来源：

MACROMOLECULES | 1993年 / 26卷 / 22期

关键词：

D O I：

10.1021/ma00074a033

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We introduce a generalized freely jointed chain and calculate analytically its partitions function and force extension relation. The generalization allows for arbitrary single segment partition functions and arbitrary dimensions. New quantitative and qualitative features of the chain are obtained for segments with internal structure. As an example we analyze the Mooney-Rivlin plot for the force elongation relation of polymer networks and find excellent agreement with experimental data.

引用

页码：6085 / 6091

页数：7

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