HIGHLY EFFICIENT PREPARATION OF OPTICALLY-ACTIVE 5-HYDROXY-3-OXOESTERS BY ENANTIOSELECTIVE REACTION OF DIKETENE WITH ALDEHYDES PROMOTED BY NOVEL CHIRAL SCHIFF BASE-TITANIUM ALKOXIDE COMPLEXES

被引：36

作者：

HAYASHI, M ^{[1
]}

TANAKA, K ^{[1
]}

OGUNI, N ^{[1
]}

机构：

[1] YAMAGUCHI UNIV,FAC SCI,DEPT CHEM,YAMAGUCHI 753,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 08期

关键词：

D O I：

10.1016/0957-4166(95)00230-M

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Optically active 5-hydroxy-3-oxoesters 1 can be obtained in up to 91% enantiomeric excess (e.e.) by the enantioselective reaction of diketene with aldehydes promoted by novel chiral Schiff base-titanium alkoxide complexes.

引用

页码：1833 / 1836

页数：4

共 17 条

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