NOVEL ENANTIOSELECTIVE REACTION OF DIKETENE WITH ALDEHYDES PROMOTED BY CHIRAL SCHIFF BASE TITANIUM ALKOXIDE COMPLEX

被引：46

作者：

HAYASHI, M ^{[1
]}

INOUE, T ^{[1
]}

OGUNI, N ^{[1
]}

机构：

[1] YAMAGUCHI UNIV,FAC SCI,DEPT CHEM,YAMAGUCHI 753,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 03期

关键词：

D O I：

10.1039/c39940000341

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of a variety of aldehydes with diketene in the presence of chiral Schiff base-titanium alkoxide complexes proceeds with high enantioselectivity to afford the corresponding 5-hydroxy-3-oxoesters.

引用

页码：341 / 342

页数：2

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