ENANTIOSELECTIVE TRIMETHYLSILYLCYANATION OF SOME ALDEHYDES BY CHIRAL TITANIUM SCHIFFS BASE COMPLEXES

被引：117

作者：

HAYASHI, M ^{[1
]}

MIYAMOTO, Y ^{[1
]}

INOUE, T ^{[1
]}

OGUNI, N ^{[1
]}

机构：

[1] YAMAGUCHI UNIV,FAC SCI,DEPT CHEM,YAMAGUCHI 753,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 24期

关键词：

D O I：

10.1039/c39910001752

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexes formed between titanium tetraalkoxide and chiral Schiff's bases make excellent catalysts for enantioselective trimethylsilylcyanation of aldehydes to optically active cyanohydrins in high optical yield.

引用

页码：1752 / 1753

页数：2

共 21 条

[1] CATALYTIC ASYMMETRIC-SYNTHESIS OF CYCLOPROPANE-CARBOXYLIC ACIDS - AN APPLICATION OF CHIRAL COPPER CARBENOID REACTION
ARATANI, T
[J]. PURE AND APPLIED CHEMISTRY, 1985, 57 (12) : 1839 - 1844
[2] ARATANI T, 1975, TETRAHEDRON LETT, P1707
[3] BECKER W, 1965, ANGEW CHEM, V77, P1139
[4] ASYMMETRIC HYDROCYANATION OF 3-PHENOXYBENZALDEHYDE CATALYZED BY POLY(CINCHONA ALKALOID-CO-ACRYLONITRILE)S
DANDA, H
CHINO, K
WAKE, S
[J]. CHEMISTRY LETTERS, 1991, (04) : 731 - 732
[5] DANDA H, 1991, SYNLETT, P263
[6] ENANTIOSELECTIVE TRIMETHYLSILYLCYANATION OF SOME ALDEHYDES PROMOTED BY MODIFIED SHARPLESS CATALYST
HAYASHI, M
MATSUDA, T
OGUNI, N
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (19) : 1364 - 1365
[7] ENANTIOSELECTIVE ADDITION-REACTION OF TRIMETHYLSILYL CYANIDE WITH ALDEHYDES USING A CHIRAL TIN(II) LEWIS ACID
KOBAYASHI, S
TSUCHIYA, Y
MUKAIYAMA, T
[J]. CHEMISTRY LETTERS, 1991, (04) : 541 - 544
[8] MATTHEWS BR, 1988, AUST J CHEM, V41, P169
[9] ASYMMETRIC HYDROCYANATION OF ALDEHYDES USING CHIRAL TITANIUM REAGENTS
MINAMIKAWA, H
HAYAKAWA, S
YAMADA, T
IWASAWA, N
NARASAKA, K
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (12) : 4379 - 4383
[10] PEPTIDE-METAL COMPLEX AS AN ASYMMETRIC CATALYST - A CATALYTIC ENANTIOSELECTIVE CYANOHYDRIN SYNTHESIS
MORI, A
NITTA, H
KUDO, M
INOUE, S
[J]. TETRAHEDRON LETTERS, 1991, 32 (34) : 4333 - 4336

← 1 2 3 →