POLYMER-BOUND LIGANDS AND METAL-COMPLEXES VIA CATALYZED-REACTIONS OF POLYBUTADIENES

被引：11

作者：

IRAQI, A ^{[1
]}

WATKINSON, M ^{[1
]}

CRAYSTON, JA ^{[1
]}

COLEHAMILTON, DJ ^{[1
]}

机构：

[1] UNIV ST ANDREWS,DEPT CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 24期

关键词：

D O I：

10.1039/c39910001767

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polybutadiene functionalised with chlorosilyl groups via homogeneous catalytic reactions can be treated with picolyl- or bipyridyl-lithium reagents to give polymer-bound ligands, which will bind metal centres chemically or electrochemically; alternatively, zinc porphyrin units can be bound to the polymer via phenolysis of the Si-Cl bonds.

引用

页码：1767 / 1769

页数：3