VIBRATIONAL-SPECTRA AND MOLECULAR-ORGANIZATION IN THIN SOLID FILMS OF 2,3-NAPHTHALOCYANINES

被引：20

作者：

GOBERNADOMITRE, I

AROCA, R

机构：

[1] UNIV WINDSOR,DEPT CHEM & BIOCHEM,MAT & SURFACE SCI GRP,WINDSOR,ON N9B 3P4,CANADA

[2] UNIV VALLADOLID,DEPT CONDENSED MATTER PHYS,E-47011 VALLADOLID,SPAIN

来源：

CHEMISTRY OF MATERIALS | 1995年 / 7卷 / 01期

关键词：

D O I：

10.1021/cm00049a018

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The spectroscopic properties and morphology of evaporated thin solid films of metal-free 2,3-naphthalocyanine (H(2)Nc) and the copper complex (CuNc) are reported. The vibrational spectra of the neat material and their films include: Raman (RS), resonance Raman (RRS), surface-enhanced resonance Raman scattering (SERRS), middle- and far-infrared spectra of the H(2)Nc and CuNc. The molecular organization of vacuum-evaporated thin films was probed by transmission and reflection-absorption FTIR spectroscopy (RAIRS). Film morphology was studied using scanning and transmission electron microscopy (SEM and TEM). Films of H2NC and CuNc were exposed to NO2, and the gas adsorption was monitored by visible absorption spectroscopy and SERRS.

引用

页码：118 / 122

页数：5

共 33 条

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[2]

Aroca R., 1991, VIBRATIONAL SPECTRA, P55

[3]

BATTISTI D, 1992, J AM CHEM SOC, V114, P4

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