NEW SYNTHESES OF PLANT ARYL GLYCOSIDES AS POTENTIAL GENE INDUCERS

被引:19
作者
DELAY, D [1 ]
DELMOTTE, F [1 ]
机构
[1] UNIV ORLEANS,F-45071 ORLEANS,FRANCE
关键词
D O I
10.1016/0008-6215(90)84294-5
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Aryl β-d-glycopyranosides have been synthesized by coupling acetovanillone (4-hydroxy-3-methoxyacetophenone) with d-glucose, d-galactose, and maltose; acetosyringone (4-hydroxy-3,5-dimethoxyacetophenone) with d-glucose and d-galactose; syringaldehyde (3-methoxyvanillin) with d-glucose; and syringic acid (4-hydroxy-3,5-dimethoxybenzoic acid) with d-glucose. The Mauthner's procedure using peracetylated glycosyl bromides and phenolates in aqueous acetone afforded the acetylated β-d-glycosides, which were deacetylated. © 1990.
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页码:223 / 234
页数:12
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