DYNAMICS OF VIBRATIONAL-EXCITATION IN MOLECULE-SURFACE INTERACTIONS

被引:38
作者
KASAI, H
OKIJI, A
机构
[1] Department of Applied Physics, Osaka University, Suita Osaka
关键词
D O I
10.1016/0079-6816(93)90003-E
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Dynamical processes of molecules interacting with solid surfaces are generally determined by geometrical structures of adiabatic potential energy surfaces, i.e., adiabatic effects, and by energy exchange processes between molecules and solid surfaces, i.e., non-adiabatic effects. In our view, molecular vibration is one of degrees of freedom particularly appropriate for investigations on origins of significant features of adiabatic and non-adiabatic effects on dynamical processes of molecules interacting with solid surfaces. From such a standpoint, a review is given of our present understanding of vibrational dynamics in molecule-surface interactions. It is divided into two parts, on the whole. In the first half, we concentrate on vibrational excitation of molecular beams interacting with solid surfaces in dynamical processes such as scattering, adsorption and desorption. In the second half, we concentrate on vibrational excitation of molecules adsorbing on metal surfaces.
引用
收藏
页码:101 / 183
页数:83
相关论文
共 81 条
[1]   ADSORPTION AND DESORPTION-KINETICS IN THE SYSTEMS H-2/CU(111), H-2/CU(110) AND H-2/CU(100) [J].
ANGER, G ;
WINKLER, A ;
RENDULIC, KD .
SURFACE SCIENCE, 1989, 220 (01) :1-17
[2]  
[Anonymous], 1960, SOV PHYS USPEKHI, DOI DOI 10.1070/PU1960V003N03ABEH003275
[3]   VIBRATIONAL AND ROTATIONAL ENERGY-DISTRIBUTION OF NO SCATTERED FROM THE PT(111) CRYSTAL-SURFACE - DETECTION BY 2-PHOTON IONIZATION [J].
ASSCHER, M ;
GUTHRIE, WL ;
LIN, TH ;
SOMORJAI, GA .
PHYSICAL REVIEW LETTERS, 1982, 49 (01) :76-79
[4]   ENERGY REDISTRIBUTION AMONG INTERNAL STATES OF NITRIC-OXIDE MOLECULES UPON SCATTERING FROM PT(111) CRYSTAL-SURFACE [J].
ASSCHER, M ;
GUTHRIE, WL ;
LIN, TH ;
SOMORJAI, GA .
JOURNAL OF CHEMICAL PHYSICS, 1983, 78 (11) :6992-7004
[5]  
AUERBACH DJ, 1984, J CHEM PHYS, V81, P2515, DOI 10.1063/1.447915
[6]   VIBRATIONAL-MODES OF HYDROGEN ADSORBED ON PT(111) - ADSORPTION SITE AND EXCITATION MECHANISM [J].
BARO, AM ;
IBACH, H ;
BRUCHMANN, HD .
SURFACE SCIENCE, 1979, 88 (2-3) :384-398
[7]   VIBRATION TRANSITIONS INDUCED BY A CHEMICAL-REACTION - QUANTUM MODEL FOR STRONG COUPLING REGION [J].
BASILEVSKY, MV .
MOLECULAR PHYSICS, 1974, 28 (03) :617-632
[8]   ULTRAFAST INFRARED RESPONSE OF ADSORBATES ON METAL-SURFACES - VIBRATIONAL LIFETIME OF CO/PT(111) [J].
BECKERLE, JD ;
CASASSA, MP ;
CAVANAGH, RR ;
HEILWEIL, EJ ;
STEPHENSON, JC .
PHYSICAL REVIEW LETTERS, 1990, 64 (17) :2090-2093
[9]   PICOSECOND IR STUDIES OF THE VIBRATIONAL DYNAMICS OF CO/PT(111) [J].
BECKERLE, JD ;
CASASSA, MP ;
HEILWEIL, EJ ;
CAVANAGH, RR ;
STEPHENSON, JC .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1990, 54 :17-26
[10]   SUBPICOSECOND TRANSIENT INFRARED-SPECTROSCOPY OF ADSORBATES - VIBRATIONAL DYNAMICS OF CO/PT(111) [J].
BECKERLE, JD ;
CAVANAGH, RR ;
CASASSA, MP ;
HEILWEIL, EJ ;
STEPHENSON, JC .
JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (07) :5403-5418