1,4-DIHYDRO-1,4-DIAZOCINE - N-SUBSTITUTION AND STRUCTURE (AROMATICITY)

被引：21

作者：

BREUNINGER, M

GALLENKAMP, B

MULLER, KH

FRITZ, H

PRINZBACH, H

DALY, JJ

SCHONHOLZER, P

机构：

[1] UNIV FREIBURG,LEHRSTUHL ORGAN CHEM,D-7800 FREIBURG,FED REP GER

[2] HOFFMANN LA ROCHE & CO AG,CH-4002 BASEL,SWITZERLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 12期

关键词：

D O I：

10.1002/anie.197909641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rings having 10 delocalizable electrons are of interest as potentially aromatic compounds. The unsubstituted 1,4‐dihydro‐1,4‐diazocine 1 has now been prepared by two independent syntheses. Some N,N′‐disubstituted derivatives of this ring system were already known. On the basis of its chemical behavior, spectra, and planar structure (confirmed by X‐ray structure analysis), 1 is to be regarded as a 10π aromatic species. No prototropic shift to give 2 or 3 is observed. The character of the N,N′‐disubstituted derivatives 4 is critically dependent upon the substituents. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：964 / 965

页数：2