ZINC-INDUCED CYCLIZATIONS OF DELTA-IODOACETYLENES

被引：20

作者：

CRANDALL, JK

AYERS, TA

机构：

[1] Department of Chemistry, Indiana University, Bloomington

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 01期

关键词：

D O I：

10.1021/om00037a079

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of delta-iodoacetylenes with zinc resulted in substantial formation of (1-iodoalkylidene)cyclopentanes, presumably via radical intermediates. These results represent the first documented example of an iodine atom-transfer cyclization in the course of the formation of an organometallic reagent.

引用

页码：473 / 477

页数：5

共 64 条

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