SOLUTION PROPERTIES OF BLOCK COPOLYMERS OF POLY(ISOPRENE - STYRENE) .2. THERMODYNAMIC PARAMETERS FROM OSMOTIC DATA

被引:9
作者
CRAMOND, DN
URWIN, JR
机构
[1] Department of Physical and Inorganic Chemistry, The University of Adelaide, Adelaide
关键词
D O I
10.1016/0014-3057(69)90102-5
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Osmotic pressure data, obtained from a study of four block copolymers, have been used to calculate second virial coefficients and number average molecular weights. The virial coefficients were determined over a range of temperatures in toluene and cyclohexane. The theta temperatures, entropy of dilution, heat of dilution and the solvent-solute interaction parameters were derived and their behaviour is discussed. © 1969.
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页码:45 / &
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