X-RAY-DIFFRACTION STUDY OF SOME MESOGENIC COPPER, NICKEL AND VANADYL COMPLEXES

被引：46

作者：

BARBERA, J

LEVELUT, AM

MARCOS, M

ROMERO, P

SERRANO, JL

机构：

[1] UNIV PARIS 11, CNRS, PHYS SOLIDES LAB, LA 2, F-91405 ORSAY, FRANCE

[2] UNIV ZARAGOZA, CSIC, FAC CIENCIAS, INST CIENCIA MAT ARAGON, E-50009 ZARAGOZA, SPAIN

来源：

LIQUID CRYSTALS | 1991年 / 10卷 / 01期

关键词：

D O I：

10.1080/02678299108028235

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present a comparative study of various metallomesogenic complexes, using X-ray diffraction methods. For a given ligand linked to different metal atoms (Cu, Ni, VO), the nature of this central atom influences mainly the magnetic susceptibilities of the mesophases. With different ligands, which keep the close neighbourhood of the metal atom unchanged, the apparent length of the mesogenic unit is longer for short ligands than for longer ones. This unexpected behaviour is qualitatively well explained by taking into account the global shape of the different complexes.

引用

页码：119 / 126

页数：8

共 16 条

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