LOW-SPIN BINUCLEAR TITANIUM COMPLEXES .2. AN INFRARED AND AN ELECTRONIC SPECTROPHOTOMETRIC STUDY OF BIS(DIMETHYLAMINO)CHLOROBORANEHEXACHLORODITITANIUM(VI)

被引：10

作者：

KYKER, GS

SCHRAM, EP

机构：

[1] Evans Chemical Laboratories, Ohio State University, Columbus

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 11期

关键词：

D O I：

10.1021/ic50081a018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The infrared spectrum of bis(dimethylamino)chloroboranehexachlorodititanium(VI), [(CH3)2N]2BCl·Ti2Cl6, is interpreted in terms of complexed dimethylamino moieties. Strong vibrational coupling in the complex results in increased v(BN) and decreased v(BCl) frequencies as compared to the free ligand. The v(TiCl) vibrations as well as the charge-transfer spectrum indicate five-coordinate Ti in [(CH3)2N]2BCl·Ti2Cl6. © 1969, American Chemical Society. All rights reserved.

引用

页码：2313 / &

共 9 条

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[6] GOUBEAU J, 1955, Z ANORG ALLGEM CHEM, V279, P83
[7] LOW-SPIN BINUCLEAR TITANIUM COMPLEXES .I. PREPARATION AND CHARACTERIZATION OF BIS(DIMETHYLAMINO)CHLOROBORANEHEXACHLORODITITANIUM(VI), [(CH3)2N]2BCL TI2CL6
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SCHRAM, EP
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[8] DI[BIS(DIMETHYLAMINO)CHLOROBORANE]TRIS-[TETRACHLOROTITANIUM(4)] . AN INFRARED STUDY
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