LOW-SPIN BINUCLEAR TITANIUM COMPLEXES .I. PREPARATION AND CHARACTERIZATION OF BIS(DIMETHYLAMINO)CHLOROBORANEHEXACHLORODITITANIUM(VI), [(CH3)2N]2BCL TI2CL6

被引：15

作者：

KYKER, GS

SCHRAM, EP

机构：

[1] Evans Chemical Laboratories, Ohio State University, Columbus

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 11期

关键词：

D O I：

10.1021/ic50081a017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of titanium tetrachloride, TiCl4, with tetrakis(dimethylamino)diborane(4), B2[N(CH3)2]4, results in formation of bis(dimethylamino)chloroboranehexachlorodititanium(VI), [(CH3)2N]2BCl·Ti2Cl6. This latter species exhibits spin equilibrium with the value for the exchange integral, J, ⋝ 378cm-1. Characterization was effected by analytical analyses, magnetic susceptibility, and reaction with N(CH3)3 affording 2TiCl3[N(CH3)3]2 and [(CH3)2N]2BCl. © 1969, American Chemical Society. All rights reserved.

引用

页码：2306 / &

共 12 条

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