THE PROPERTIES OF PALLADIUM ELECTRODES FOR ELECTROOXIDATION OF ETHYLENE-GLYCOL

被引：32

作者：

DALBAY, N ^{[1
]}

KADIRGAN, F ^{[1
]}

机构：

[1] ISTANBUL TECH UNIV,FAK FEN EDEBIYAT,80626 MASLAK,ISTANBUL,TURKEY

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1990年 / 296卷 / 02期

关键词：

D O I：

10.1016/0022-0728(90)87272-L

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In order to interpret the electrocatalytic properties of palladium for the oxidation of ethylene glycol, a mechanistic investigation was carried out in alkaline medium. The kinetic parameters, estimated from electrochemical data, suggest a one electron step to be rate determining, and the rate of the reaction depends directly on the pH.

引用

页码：559 / 569

页数：11

共 19 条

[1]

ADZIC RR, 1982, B SOC CHIM BELGRADE, V47, P83

[2] THE OXIDATION OF ETHYLENE-GLYCOL AT A PLATINUM-ELECTRODE IN ACID AND BASE - AN INSITU FTIR STUDY [J].

CHRISTENSEN, PA ;

HAMNETT, A .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 260 (02) :347-359

[3]

CNOBLOCH H, 1979, POWER SOURCES 7, V24, P389

[4]

CNOBLOCH H, 1982, PROG BATT SOLAR CELL, V4, P225

[5]

DALBAY N, IN PRESS ELECTROCHIM

[6] ETHYLENE-GLYCOL AS FUEL FOR ALKALINE FUEL-CELLS [J].

EWE, H ;

JUSTI, E ;

PESDITSCHEK, M .

ENERGY CONVERSION, 1975, 15 (1-2) :9-14

[7] ELECTROOXIDATION OF ETHYLENEGLYCOL AT GOLD IN POTASSIUM HYDROXIDE [J].

HAUFFE, W ;

HEITBAUM, J .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1978, 82 (05) :487-491

[8] ELECTROOXIDATION OF ETHYLENE-GLYCOL AT PLATINUM IN POTASSIUM HYDROXIDE [J].

HAUFFE, W ;

HEITBAUM, J .

ELECTROCHIMICA ACTA, 1978, 23 (04) :299-304

[9]

HAUFFE W, 1977, ELECTRODE MATERIALS, P308

[10] ELECTROCATALYTIC OXIDATION OF ETHYLENE-GLYCOL .2. BEHAVIOR OF PLATINUM-AD-ATOM ELECTRODES IN ALKALINE-MEDIUM [J].

KADIRGAN, F ;

BEDEN, B ;

LAMY, C .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1983, 143 (1-2) :135-152

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