OBSERVATION OF A MEMORY EFFECT IN THE CASE OF POLY(P-PHENYLENE), SYNTHESIZED BY ELECTROCHEMICAL OXIDATION OF BENZENE IN A SUPERACID MEDIUM

被引:14
作者
GOLDENBERG, LM [1 ]
AEIYACH, S [1 ]
LACAZE, PC [1 ]
机构
[1] UNIV PARIS 07,CNRS,INST TOPOL & DYNAM SYST,1 RUE GUY BROSSE,F-75221 PARIS 05,FRANCE
关键词
D O I
10.1016/0379-6779(93)90252-R
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The voltammetric behaviour of poly(p-phenylene) obtained by oxidation of benzene in trifluoromethanesulfonic acid solution has been tested in different electrolytes. For the first time we show a relaxation effect (the so called ''memory effect'') characterized by a logarithmic law between the voltammogram parameters and the waiting time in the neutral state (at 0 V vs Ag/AgCl).
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页码:1365 / 1370
页数:6
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