ANODIC INFRARED SPECTROELECTROCHEMISTRY OF MONONUCLEAR AND DINUCLEAR COMPLEXES CONTAINING THE (ETA(5)-C(5)H(4)R)MN(CO)(2)L MOIETY (L=CO OR PR(3))

被引：34

作者：

ATWOOD, CG ^{[1
]}

GEIGER, WE ^{[1
]}

BITTERWOLF, TE ^{[1
]}

机构：

[1] UNIV IDAHO,DEPT CHEM,MOSCOW,ID 83844

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1995年 / 397卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

MANGANESE CARBONYL COMPLEXES; ANODIC INFRARED SPECTROELECTROCHEMISTRY;

D O I：

10.1016/0022-0728(95)04201-X

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A series of manganese and dimanganese organometallic complexes containing carbonyl ligands were studied by voltammetry, coulometry and IR spectroelectrochemistry. One-electron oxidations to cations were reversible at sub-ambient temperatures in dichloromethane for all complexes incorporating a phosphine ligand, two such processes being observed for the dinuclear complexes. The mono- and dications were characterized by IR spectroelectrochemistry using a thin-layer cell in the transmission mode. Good results were obtained for dichloromethane solutions with temperatures as low as 213 K. All of the mixed-valent monocations of the di-manganese complexes exhibited trapped valency.

引用

页码：279 / 285

页数：7

共 45 条

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