ANODIC INFRARED SPECTROELECTROCHEMISTRY OF MONONUCLEAR AND DINUCLEAR COMPLEXES CONTAINING THE (ETA(5)-C(5)H(4)R)MN(CO)(2)L MOIETY (L=CO OR PR(3))

被引：34

作者：

ATWOOD, CG ^{[1
]}

GEIGER, WE ^{[1
]}

BITTERWOLF, TE ^{[1
]}

机构：

[1] UNIV IDAHO,DEPT CHEM,MOSCOW,ID 83844

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1995年 / 397卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

MANGANESE CARBONYL COMPLEXES; ANODIC INFRARED SPECTROELECTROCHEMISTRY;

D O I：

10.1016/0022-0728(95)04201-X

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A series of manganese and dimanganese organometallic complexes containing carbonyl ligands were studied by voltammetry, coulometry and IR spectroelectrochemistry. One-electron oxidations to cations were reversible at sub-ambient temperatures in dichloromethane for all complexes incorporating a phosphine ligand, two such processes being observed for the dinuclear complexes. The mono- and dications were characterized by IR spectroelectrochemistry using a thin-layer cell in the transmission mode. Good results were obtained for dichloromethane solutions with temperatures as low as 213 K. All of the mixed-valent monocations of the di-manganese complexes exhibited trapped valency.

引用

页码：279 / 285

页数：7

共 45 条

[41] TETRAALKYLAMMONIUM TRIFLUOROMETHANE-SULFONATES AS SUPPORTING ELECTROLYTES
ROUSSEAU, K
FARRINGT.GC
DOLPHIN, D
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1972, 37 (24) : 3968 - &
[42] STUDIES OF MIXED-VALENCE DIFERROCENYL SELENIDE AND DIFERROCENYL DISELENIDE
SHU, P
BECHGAARD, K
COWAN, DO
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (10) : 1849 - 1852
[43] STROHMEIER W, 1962, Z NATURFORSCH PT B, VB 17, P848
[44] INTRAMOLECULAR, OUTER-SPHERE ELECTRON-TRANSFER IN THE MIXED-VALENCE ION [(BPY)2CLRU(PH2PCH2PPH2)RUCL(BPY)2]3+
SULLIVAN, BP
MEYER, TJ
[J]. INORGANIC CHEMISTRY, 1980, 19 (03) : 752 - 755
[45] STRUCTURAL CONSEQUENCES OF ELECTRON-TRANSFER REACTIONS .15. MIXED-VALENT CATIONS OF DINUCLEAR CHROMIUM ARYL COMPLEXES - ELECTROCHEMICAL, SPECTROSCOPIC, AND STRUCTURAL CONSIDERATIONS
VANORDER, N
GEIGER, WE
BITTERWOLF, TE
RHEINGOLD, AL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (19) : 5680 - 5690

← 1 2 3 4 5 →