STEROIDAL DERIVATIVES FROM THE ROOTS OF MANDEVILLA-PENTLANDIANA

被引:15
作者
CABRERA, G [1 ]
PALERMO, JA [1 ]
SELDES, AM [1 ]
GROS, EG [1 ]
OBERTI, JC [1 ]
机构
[1] NATL UNIV CORDOBA,FAC CIENCIAS QUIM,DEPT QUIM ORGAN,RA-5016 CORDOBA,ARGENTINA
关键词
MANDEVILLA-PENTLANDIANA; APOCYNACEAE; ROOTS; DELTA-5,20-DIUNSATURATED STEROLS; 6-KETO-5-ALPHA-STANOLS;
D O I
10.1016/S0031-9422(00)95209-9
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The steroids from the roots of Mandevilla pentlandiana were analysed. Six DELTA-20-steroids and four 6-keto-5-alpha-stanols, novel as natural products, were isolated and characterized by spectroscopic methods. The plant also produces cardenolide glycosides, for which 20-hydroxysterols are known to be biosynthetic precursors. The hydroxylated derivatives have not been detected, but DELTA-20-derivatives, closely related to them, may be involved in that metabolic pathway.
引用
收藏
页码:1239 / 1243
页数:5
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