SYNTHESIS AND STRUCTURE OF ORGANOMETALLIC COMPOUNDS WITH (AL2SI)(2) AND AL3SB2 FRAMEWORKS

被引：56

作者：

SCHULZ, S ^{[1
]}

SCHOOP, T ^{[1
]}

ROESKY, HW ^{[1
]}

HAMING, L ^{[1
]}

STEINER, A ^{[1
]}

HERBSTIRMER, R ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 08期

关键词：

ALUMINUM COMPOUNDS; ANTIMONY COMPOUNDS; MAIN GROUP ELEMENTS; SILICON COMPOUNDS;

D O I：

10.1002/anie.199509191

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A complex with an eight‐membered Al4F4 ring in which pairs of Al atoms are bridged by Ph2Si units is the unexpected product of the reaction of [(Cp*Al)4] with Ph2SiF2[Eq. (a)]. The formation of 1 can be explained in terms of the marked fluorophilicity of [(Cp*Al)4]. Reaction of [(Cp*Al)4] with (tBuSb)4 yields [(Cp*Al)3Sb2], the first organometallic compound to contain an aluminium‐antimony bond. (Formula Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：919 / 920

页数：2

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