STEREOSELECTIVE SYNTHESIS AND STEREOCHEMICAL DETERMINATION OF 2,5-DIALKLPYRROLIDINES AND 2,6-DIALKYLPIPERIDINES

被引:29
作者
BACOS, D [1 ]
CELERIER, JP [1 ]
MARX, E [1 ]
ROSSET, S [1 ]
LHOMMET, G [1 ]
机构
[1] UNIV PARIS 06, URA 455, F-75252 PARIS 05, FRANCE
关键词
D O I
10.1002/jhet.5570270538
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
ω‐Alkyllactams 3 can be transformed into ω‐alkyl cyclic β‐enaminoesters 7 which are good precursors of insects venom alkaloids. A stereoselective synthesis of dialkylpyrrolidines and Solenopsine A is described followed by an easy stereochemical determination by 13C nmr. Copyright © 1990 Journal of Heterocyclic Chemistry
引用
收藏
页码:1387 / 1392
页数:6
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