STEREOSELECTIVE SYNTHESIS AND STEREOCHEMICAL DETERMINATION OF 2,5-DIALKLPYRROLIDINES AND 2,6-DIALKYLPIPERIDINES

被引：29

作者：

BACOS, D ^{[1
]}

CELERIER, JP ^{[1
]}

MARX, E ^{[1
]}

ROSSET, S ^{[1
]}

LHOMMET, G ^{[1
]}

机构：

[1] UNIV PARIS 06, URA 455, F-75252 PARIS 05, FRANCE

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1990年 / 27卷 / 05期

关键词：

D O I：

10.1002/jhet.5570270538

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

ω‐Alkyllactams 3 can be transformed into ω‐alkyl cyclic β‐enaminoesters 7 which are good precursors of insects venom alkaloids. A stereoselective synthesis of dialkylpyrrolidines and Solenopsine A is described followed by an easy stereochemical determination by 13C nmr. Copyright © 1990 Journal of Heterocyclic Chemistry

引用

页码：1387 / 1392

页数：6