CLUSTER CHEMISTRY .73. PREPARATION AND X-RAY STRUCTURE OF THE HEXANUCLEAR COBALT-RUTHENIUM CLUSTER, CORU5(MU-4-PPH) (MU-4-C2PH)(MU-PPH2)(CO)12(ETA-C5H5)

被引：7

作者：

ADAMS, CJ ^{[1
]}

BRUCE, MI ^{[1
]}

SKELTON, BW ^{[1
]}

WHITE, AH ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 420卷 / 01期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/0022-328X(91)86449-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One of the products from the reaction between Ru5(mu-5-C2PPh2)(mu-PPh2)(CO)13 and Co(CO)2(eta-C5H5) is the heterometallic CoRu5 cluster, CoRu5(mu-4-PPh)(mu-4-C2Ph)(mu-PPh2)(CO)12(eta-C5H5). The Ru5 core has an irregular envelope conformation, one edge of which is bridged by PPh2; the Co is attached to three Ru atoms of the Ru4 rhombus, the other side of which is capped by PPh. A C2Ph ligand, formed by extrusion of PPh to the cluster, bridges the flap of the envelope and the Co atom, and also interacts with three Ru atoms.

引用

页码：95 / 103

页数：9

共 16 条

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