SOME REMARKABLE REACTIONS OF AN OPEN RU5 CLUSTER

被引：26

作者：

BRUCE, MI

机构：

[1] Jordan Laboratories, Department of Physical and Inorganic Chemistry, University of Adelaide, Adelaide

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 394卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(90)87245-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The current status of our studies of the chemistry of the complex Ru5(μ5-C2PPh2)(μ-PPh2)(CO)13, which contains an open Ru5 cluster interacting with the diphenylphosphinoethynyl group, is summarised. Ready cleavage of the CP bond occurs, to give a cluster-bound C2 unit which undergoes a number of remarkable reactions and there are concomitant rearrangements of the metal core. © 1990.

引用

页码：365 / 384

页数：20

共 47 条

[1] ADAMS CJ, UNPUB
[2] ACTIVATION OF HETERONUCLEAR TRIPLE BONDS BY CLUSTER COMPOUNDS - THE CLEAVAGE OF THE C-N TRIPLE BOND OF AN ISOCYANIDE LIGAND BY A RUTHENIUM CLUSTER
ADAMS, RD
MATHUR, P
SEGMULLER, BE
[J]. ORGANOMETALLICS, 1983, 2 (09) : 1258 - 1259
[3] CLUSTER SYNTHESIS .17. SYNTHESIS AND STRUCTURAL CHARACTERIZATIONS OF RU5(CO)15(MU-4-S), RU6(CO)18(MU-4-S), AND RU7(CO)21(MU-4-S)
ADAMS, RD
BABIN, JE
TASI, M
[J]. ORGANOMETALLICS, 1988, 7 (02) : 503 - 513
[4] RELATION BETWEEN BONDING AND THE SUBSTITUTION-DEPENDENT GEOMETRY OF A NUMBER OF DICOBALT HEXACARBONYL ACETYLENE COMPLEXES
BAERT, F
GUELZIM, A
COPPENS, P
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1984, 40 (DEC): : 590 - 595
[5] OXIDATIVE ADDITION-REACTIONS OF TRIPHENYLPHOSPHINE WITH DODECACARBONYL-TRIOSMIUM(O) - BENZENE-COMPLEXES, PHENYL-COMPLEXES AND RELATED COMPLEXES OF OSMIUM
BRADFORD, CW
MASON, R
GAINSFORD, GJ
GUSS, JM
NYHOLM, RS
IRELAND, PR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (02) : 87 - +
[6] OXIDATIVE ADDITION-REACTIONS OF TRIPHENYLPHOSPHINE WITH DODECACARBONYLTRIOSMIUM
BRADFORD, CW
NYHOLM, RS
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (05): : 529 - 533
[7] CLUSTER CHEMISTRY .17. RADICAL ION INITIATED SYNTHESES OF RUTHENIUM CLUSTER CARBONYLS CONTAINING TERTIARY PHOSPHINES, PHOSPHITES, ARSINES, SBPH3 OR ISOCYANIDES
BRUCE, MI
MATISONS, JG
NICHOLSON, BK
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 247 (03) : 321 - 343
[8] CLUSTER CHEMISTRY .34. REACTIONS OF AN OPEN RU5 CLUSTER WITH CO - X-RAY STRUCTURES OF 2 ISOMERS OF [RU5(MU-5-C2PPH2)(MU-PPH2)(CO)15]
BRUCE, MI
WILLIAMS, ML
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 282 (01) : C11 - C16
[9] CLUSTER CHEMISTRY - STEPWISE HYDROGENATION OF AN ACETYLIDE LIGAND TO CARBON AND METHYL ON A RU5 CLUSTER - X-RAY STRUCTURES OF [RU5(MU-H)(MU-5-C=CHPPH2)(MU-PPH2)(CO)13] AND [RU5C(MU-H)3(MU-PPH2)(CO)11(PMEPH2)]
BRUCE, MI
SKELTON, BW
WHITE, AH
WILLIAMS, ML
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (11) : 744 - 745
[10] CLUSTER CHEMISTRY - SYNTHESIS AND X-RAY STRUCTURE OF [RU5(CO)14(CNBU-T)2], CONTAINING AN UNUSUAL OPEN RU5 CLUSTER
BRUCE, MI
MATISONS, JG
RODGERS, JR
WALLIS, RC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (20) : 1070 - 1071

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