SOME REMARKABLE REACTIONS OF AN OPEN RU5 CLUSTER

被引：26

作者：

BRUCE, MI

机构：

[1] Jordan Laboratories, Department of Physical and Inorganic Chemistry, University of Adelaide, Adelaide

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 394卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(90)87245-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The current status of our studies of the chemistry of the complex Ru5(μ5-C2PPh2)(μ-PPh2)(CO)13, which contains an open Ru5 cluster interacting with the diphenylphosphinoethynyl group, is summarised. Ready cleavage of the CP bond occurs, to give a cluster-bound C2 unit which undergoes a number of remarkable reactions and there are concomitant rearrangements of the metal core. © 1990.

引用

页码：365 / 384

页数：20

共 47 条

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