SYNTHESIS AND 2ND-ORDER NONLINEAR-OPTICAL PROPERTIES OF NEW BIPYRIDYL METAL-COMPLEXES

被引：46

作者：

BOURGAULT, M

MOUNTASSIR, C

LEBOZEC, H

LEDOUX, I

PUCETTI, G

ZYSS, J

机构：

[1] UNIV RENNES 1,CHIM COORDINAT ORGAN LAB,CNRS,URA 415,CAMPUS BEAULIEU,F-35042 RENNES,FRANCE

[2] FRANCE TELECOM,CNET,BAGNEUX LAB,CTR PARIS B,CNRS,URA 250,F-92220 BAGNEUX,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 21期

关键词：

D O I：

10.1039/c39930001623

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and characterisation of a series of new pi-donor substituted vinyl bipyridines and their rhenium, zinc and mercury complexes {donor = 4-R2N-C6H4- [R2N = Me2N, Bun2N, (Me)(OCt(n)N)]; (eta5-C5H5)Fe(eta5-C5H4-)} with large nonlinear optical properties are presented; EFISH experiments at 1.34 mum show that complexation leads to a strong enhancement (by a factor of 3 to 9) of the molecular hyperpolarisability beta(0).

引用

页码：1623 / 1624

页数：2