A MODEL FOR ALPHA-KETO ACID-DEPENDENT NONHEME IRON ENZYMES - STRUCTURE AND REACTIVITY OF [FE-2(II)(ME(2)HDP)(2)(BF)](CLO4)

被引：13

作者：

CHIOU, YM ^{[1
]}

QUE, L ^{[1
]}

机构：

[1] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 18期

关键词：

D O I：

10.1002/anie.199418861

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bis(μ‐phenolato)diiron(II) complex 1 is a model compound for nonheme iron enzymes that use α‐keto acids as cofactors. Complex 1 undergoes immediate oxidative decarboxylation upon exposure to dioxygen at a rate which is three to four orders of magnitude faster than those observed for other compounds of this type. The formula of the ligand is given under that of 1. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1886 / 1888

页数：3

共 32 条

[21] ALTERNATE SUBSTRATES AND INHIBITORS OF BACTERIAL 4-HYDROXYPHENYLPYRUVATE DIOXYGENASE
PASCAL, RA
OLIVER, MA
CHEN, YCJ
[J]. BIOCHEMISTRY, 1985, 24 (13) : 3158 - 3165
[22] MODEL STUDIES OF IRON TYROSINATE PROTEINS
PYRZ, JW
ROE, AL
STERN, LJ
QUE, L
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (03) : 614 - 620
[23] CHARACTERIZATION OF 4-HYDROXYPHENYLPYRUVATE DIOXYGENASE - PRIMARY STRUCTURE OF THE PSEUDOMONAS ENZYME
RUETSCHI, U
ODELHOG, B
LINDSTEDT, S
BARROSSODERLING, J
PERSSON, B
JORNVALL, H
[J]. EUROPEAN JOURNAL OF BIOCHEMISTRY, 1992, 205 (02): : 459 - 466
[24] HUMAN 4-HYDROXPHENYLPYRUVATE DIOXYGENASE - PRIMARY STRUCTURE AND CHROMOSOMAL LOCALIZATION OF THE GENE
RUETSCHI, U
DELLSEN, A
SAHLIN, P
STENMAN, G
RYMO, L
LINDSTEDT, S
[J]. EUROPEAN JOURNAL OF BIOCHEMISTRY, 1993, 213 (03): : 1081 - 1089
[25] BINUCLEAR COMPLEXES OF MACROCYCLIC LIGANDS - VARIATION OF MAGNETIC EXCHANGE INTERACTION IN A SERIES OF 6-COORDINATE IRON(II), COBALT(II), AND NICKEL(II) COMPLEXES AND THE X-RAY STRUCTURE OF A BINUCLEAR IRON(II) MACROCYCLIC LIGAND COMPLEX
SPIRO, CL
LAMBERT, SL
SMITH, TJ
DUESLER, EN
GAGNE, RR
HENDRICKSON, DN
[J]. INORGANIC CHEMISTRY, 1981, 20 (04) : 1229 - 1237
[26] SYNTHESIS, STRUCTURE, AND ELECTRONIC CHARACTERIZATION OF REACTIVE DIIRON(II) 1,2-BIS(2-HYDROXYBENZAMIDO)BENZENE COMPLEXES AS MODELS FOR METHANE MONOOXYGENASE
STASSINOPOULOS, A
SCHULTE, G
PAPAEFTHYMIOU, GC
CARADONNA, JP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) : 8686 - 8697
[27] Synder B. S., 1989, J AM CHEM SOC, V111, P5214
[28] [FE(OME)(2)(O2CCH2CL)](10), A MOLECULAR FERRIS WHEEL
TAFT, KL
DELFS, CD
PAPAEFTHYMIOU, GC
FONER, S
GATTESCHI, D
LIPPARD, SJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) : 823 - 832
[29] MODELS OF THE REDUCED FORMS OF POLYIRON-OXO PROTEINS - AN ASYMMETRIC, TRIPLY CARBOXYLATE BRIDGED DIIRON(II) COMPLEX AND ITS REACTION WITH DIOXYGEN
TOLMAN, WB
LIU, SC
BENTSEN, JG
LIPPARD, SJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) : 152 - 164
[30] THE ACTIVE-SITES IN MANGANESE-CONTAINING METALLOPROTEINS AND INORGANIC MODEL COMPLEXES
WIEGHARDT, K
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1989, 28 (09) : 1153 - 1172

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