CHEMICAL-REACTION RATES AND SOLVATION DYNAMICS IN ELECTROLYTE-SOLUTIONS - ION ATMOSPHERE FRICTION

被引：82

作者：

VANDERZWAN, G ^{[1
]}

HYNES, JT ^{[1
]}

机构：

[1] UNIV COLORADO,DEPT CHEM & BIOCHEM,BOULDER,CO 80309

来源：

CHEMICAL PHYSICS | 1991年 / 152卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0301-0104(91)80043-H

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We consider the influence of ion atmosphere dynamics on a model dipolar isomerization in an electrolyte solution, as well as on the time dependent fluorescence (TDF) of a dipolar solute. The impact of the resulting ion atmosphere friction on reducing the reaction rate below the equilibrium solvation transition state theory value can sometimes be pronounced. Connections of this friction to the TDF dynamics are indicated for solvents both of low and high polarity.

引用

页码：169 / 183

页数：15

共 64 条

[51] SOLVENT DIELECTRIC EFFECTS ON ISOMERIZATION DYNAMICS - INVESTIGATION OF THE PHOTOISOMERIZATION OF 4,4'-DIMETHOXYSTILBENE AND TERT-STILBENE IN NORMAL-ALKYL NITRILES
SIVAKUMAR, N
HOBURG, EA
WALDECK, DH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (04) : 2305 - 2316
[52] DIFFUSION-CONTROLLED REACTIONS OF IONS IN FLUCTUATING IONIC ATMOSPHERES
SRIDHARAN, S
MCCAMMON, JA
HUBBARD, JB
[J]. JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (01) : 237 - 240
[53] TRIOLO R, 1981, ADV SOLUTION CHEM
[54] Turq P., 1987, Physics and Chemistry of Aqueous Ionic Solutions. Proceedings of the NATO Advanced Study Institute, P409
[55] NON-EQUILIBRIUM SOLVATION DYNAMICS IN SOLUTION REACTIONS
VANDERZWAN, G
HYNES, JT
[J]. JOURNAL OF CHEMICAL PHYSICS, 1983, 78 (06) : 4174 - 4185
[56] POLARIZATION DIFFUSION EFFECTS ON REACTION-RATES IN POLAR-SOLVENTS
VANDERZWAN, G
HYNES, JT
[J]. CHEMICAL PHYSICS LETTERS, 1983, 101 (4-5) : 367 - 371
[57] DYNAMICAL POLAR-SOLVENT EFFECTS ON SOLUTION REACTIONS - A SIMPLE CONTINUUM MODEL
VANDERZWAN, G
HYNES, JT
[J]. JOURNAL OF CHEMICAL PHYSICS, 1982, 76 (06) : 2993 - 3001
[58] TIME-DEPENDENT FLUORESCENCE SOLVENT SHIFTS, DIELECTRIC FRICTION, AND NONEQUILIBRIUM SOLVATION IN POLAR-SOLVENTS
VANDERZWAN, G
HYNES, JT
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (20) : 4181 - 4188
[59] A SIMPLE DIPOLE ISOMERIZATION MODEL FOR NON-EQUILIBRIUM SOLVATION DYNAMICS IN REACTIONS IN POLAR-SOLVENTS
VANDERZWAN, G
HYNES, JT
[J]. CHEMICAL PHYSICS, 1984, 90 (1-2) : 21 - 35
[60] VANDERZWAN G, UNPUB

← 1 2 3 4 5 6 7 →