PALLADIUM-CATALYZED ALKOXYCARBONYLATION OF TRICARBONYL(ETA-6-MONO AND DICHLOROARENE)CHROMIUM COMPLEXES UNDER MILD CONDITIONS USING HCO2R/MOR SYSTEM

被引：36

作者：

CARPENTIER, JF ^{[1
]}

CASTANET, Y ^{[1
]}

BROCARD, J ^{[1
]}

MORTREUX, A ^{[1
]}

PETIT, F ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM LILLE,CNRS,CHIM ORGAN APPLIQUEE LAB,BP 108,F-59652 VILLENEUVE DASCQ,FRANCE

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 15期

关键词：

ALKOXYCARBONYLATION; ARENES-CHROME; FORMATE; PALLADIUM;

D O I：

10.1016/0040-4039(92)88124-N

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkoxycarbonylation competes with nucleophilic aromatic substitution and palladium-catalysed reduction during treatment of Cr(CO)3-complexed chloroarenes with HCO2R / MOR / PdCl2(PPh3)2. The influence of the nature of the HCO2R / MOR system and of stereoelectronic factors in dichlorobenzene complexes are discussed.

引用

页码：2001 / 2004

页数：4

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