STUDIES ON THE OXIDATION OF ALCOHOLS EMPLOYING T-BUTYL HYDROPEROXIDE (TBHP) AND FE(III) CATALYSTS

被引：22

作者：

BARTON, DHR

BEVIERE, SD

CHABOT, BM

CHAVASIRI, W

TAYLOR, DK

机构：

[1] M University, College Station

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 27期

关键词：

D O I：

10.1016/S0040-4039(00)76940-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New methodology for the oxidation of alcohols to ketones in good yield utilizing catalytic amounts of Fe-III salts and TBHP as the oxidant is highlighted. Competition between alcohol and hydrocarbon oxidation has been clearly demonstrated. The ''normal'' Gif-type solvent system (pyridine/acetic acid) can be replaced by the alcohol itself.

引用

收藏

页码：4681 / 4684

页数：4

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