THE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .24. THE USE OF TERT-BUTYL HYDROPEROXIDE - GOAGG(IV) AND GOAGG(V)

被引：52

作者：

BARTON, DHR

CHAVASIRI, W

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

TETRAHEDRON | 1994年 / 50卷 / 01期

基金：

美国国家科学基金会;

关键词：

GIF SYSTEMS; ACTIVATION OF ALKANES; SELECTIVE FUNCTIONALIZATION; TERT-BUTYL HYDROPEROXIDE;

D O I：

10.1016/S0040-4020(01)80734-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The use of tert-butyl hydroperoxide as an oxidant in Gif-type systems (GoAgg(IV) and GoAgg(V)) catalyzed by various Fe(III) species is examined. Regioselectivity studies of these systems have revealed several characteristics similar to those observed for other previously reported Gif-type reactions. A common reaction pathway for the GoAgg(IV) and GoAgg(V) oxidation systems and other Gif-type reactions (from alkane via alkyl hydroperoxide to ketone or alcohol) is seen.

引用

页码：19 / 30

页数：12

共 55 条

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[8] THE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .20. ALKYL HYDROPEROXIDES - REACTION INTERMEDIATES IN THE OXIDATION OF SATURATED-HYDROCARBONS BY GIF-TYPE REACTIONS AND MECHANISTIC STUDIES ON THEIR FORMATION
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