THE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .24. THE USE OF TERT-BUTYL HYDROPEROXIDE - GOAGG(IV) AND GOAGG(V)

被引：52

作者：

BARTON, DHR

CHAVASIRI, W

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

TETRAHEDRON | 1994年 / 50卷 / 01期

基金：

美国国家科学基金会;

关键词：

GIF SYSTEMS; ACTIVATION OF ALKANES; SELECTIVE FUNCTIONALIZATION; TERT-BUTYL HYDROPEROXIDE;

D O I：

10.1016/S0040-4020(01)80734-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The use of tert-butyl hydroperoxide as an oxidant in Gif-type systems (GoAgg(IV) and GoAgg(V)) catalyzed by various Fe(III) species is examined. Regioselectivity studies of these systems have revealed several characteristics similar to those observed for other previously reported Gif-type reactions. A common reaction pathway for the GoAgg(IV) and GoAgg(V) oxidation systems and other Gif-type reactions (from alkane via alkyl hydroperoxide to ketone or alcohol) is seen.

引用

页码：19 / 30

页数：12

共 55 条

[21] REACTION OF LITHIUM ALKYLS WITH ALDEHYDES AND KETONES - GENERAL STUDY
BUHLER, JD
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1973, 38 (05) : 904 - 906
[22] REDUCTION WITH METAL HYDRIDES .19. COMPETITIVE REDUCTION OF ALKYLCYCLOHEXANONES - REGARDING CONCEPTS OF STERIC APPROACH CONTROL AND PRODUCT DEVELOPMENT CONTROL
ELIEL, EL
SENDA, Y
[J]. TETRAHEDRON, 1970, 26 (10) : 2411 - &
[23] ELIEL EL, 1967, ORG SYN, V47, P16
[24] SUSTAINED CATALYTIC HOMOGENOUS OXO-TRANSFER OXIDATION OF ALKANES - INTERACTION OF ALKYL HYDROPEROXIDES WITH TRANSITION METAL-SUBSTITUTED POLYOXOMETALATES
FARAJ, M
HILL, CL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (19) : 1487 - 1489
[25] CARBON HYDROGEN ACTIVATION CHEMISTRY - HYDROXYLATION OF C2, C-3, AND CYCLO-C6 HYDROCARBONS BY MANGANESE CLUSTER CATALYSTS WITH A MONO-OXYGEN TRANSFER REAGENT
FISH, RH
FONG, RH
VINCENT, JB
CHRISTOU, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (22) : 1504 - 1506
[26] ALKANE OXIDATION BY POLYNUCLEAR NONHEME IRON COMPLEXES - AN IMIDAZOLE EFFECT
FONTECAVE, M
ROY, B
LAMBEAUX, C
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (14) : 939 - 940
[27] Fox B. G., 1990, BIOL OXIDATION SYSTE, V1, P367
[28] SYNTHESIS, STRUCTURE, AND PROPERTIES OF AN UNDECAIRON(III) OXO-HYDRO AGGREGATE - AN APPROACH TO THE POLYIRON CORE IN FERRITIN
GORUN, SM
PAPAEFTHYMIOU, GC
FRANKEL, RB
LIPPARD, SJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (11) : 3337 - 3348
[29] JEFCOATE CR, 1986, STRUCTURE MECH BIOCH, P387
[30] HYDROXYLATION OF ALKANES AND ARENES USING MOLECULAR-OXYGEN
KITAJIMA, N
ITO, M
FUKUI, H
MOROOKA, Y
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (02) : 102 - 104

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