ESR SPECTRA AND CONFORMATIONS OF ALICYCLIC FREE RADICALS PRODUCED IN REDOX SYSTEMS

被引：22

作者：

CORVAJA, C

BRUSTOLO.M

GIACOMET.G

机构：

[1] Istituto di Chimica Fisica, Università Padova Italy

来源：

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT | 1969年 / 66卷 / 4-6期

关键词：

D O I：

10.1524/zpch.1969.66.4_6.279

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A number of pentatomic and hexatomic alicyclic free radical Systems are investigated through their ESR speetra obtained in a flow System by the action of different redox Systems. The hyperfine Splitting constants of the radicals are interpreted in terms of existing theories and of plausible conformations of the rings. An effect of electronegative atoms on McConnell's Q value for the radicalic carbon atom in noted and discussed. © 1969, Walter de Gruyter. All rights reserved.

引用

页码：279 / &

共 26 条

[1] BOLTON RJ, 1962, MOLECULAR PHYSICS, V5, P31
[2] THE CONFORMATIONS OF SUBSTITUTED CYCLOPENTANES .1. THE INFRARED ANALYSIS AND STRUCTURE OF THE ALPHA-HALOCAMPHORS, THE ALPHA-HALO-2-INDANONES AND THE ALPHA-HALOCYCLOPENTANONES
BRUTCHER, FV
ROBERTS, T
BARR, SJ
PEARSON, N
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (18) : 4915 - 4920
[3] ELECTRON SPIN RESONANCE STUDIES OF OXIDATION .8. ELIMINATION REACTIONS OF SOME HYDROXYALKYL RADICALS
BULEY, AL
NORMAN, ROC
PRITCHETT, RJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1966, (09): : 849 - +
[4] HYPERFINE COUPLING CONSTANTS OF CH2 PROTONS IN PARAMAGNETIC AROMATIC SYSTEMS - SPIN POLARIZATION VERSUS HYPERCONJUGATION
COLPA, JP
DEBOER, E
[J]. MOLECULAR PHYSICS, 1964, 7 (04) : 333 - &
[5] ESR SPECTRA OF RADICAL OBTAINED BY ADDITION OF NH2 AND OF CH20H TO VINYL COMPOUNDS
CORVAJA, C
FISCHER, H
GIACOMET.G
[J]. ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1965, 45 (1-2): : 1 - &
[6] ELECTRON SPIN RESONANCE STUDIES OF OXIDATION .3. SOME ALICYCLIC COMPOUNDS
DIXON, WT
NORMAN, ROC
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1964, (DEC): : 4850 - &
[7] ELECTRON SPIN RESONANCE STUDIES OF OXIDATION .1. ALCOHOLS
DIXON, WT
NORMAN, ROC
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1963, (MAY): : 3119 - &
[8] ELECTRON SPIN RESONANCE STUDIES OF TRANSIENT ALKYL RADICALS
FESSENDEN, RW
SCHULER, RH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1963, 39 (09) : 2147 - &
[9] ELECTRON SPIN RESONANCE SPECTRA OF SOME ISOTOPICALLY SUBSTITUTED HYDROCARBON RADICALS
FESSENDEN, RW
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (01) : 74 - +
[10] FISCHER H, 1964, Z NATURFORSCH PT A, VA 19, P866

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