ESR SPECTRA AND CONFORMATIONS OF ALICYCLIC FREE RADICALS PRODUCED IN REDOX SYSTEMS

被引：22

作者：

CORVAJA, C

BRUSTOLO.M

GIACOMET.G

机构：

[1] Istituto di Chimica Fisica, Università Padova Italy

来源：

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT | 1969年 / 66卷 / 4-6期

关键词：

D O I：

10.1524/zpch.1969.66.4_6.279

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A number of pentatomic and hexatomic alicyclic free radical Systems are investigated through their ESR speetra obtained in a flow System by the action of different redox Systems. The hyperfine Splitting constants of the radicals are interpreted in terms of existing theories and of plausible conformations of the rings. An effect of electronegative atoms on McConnell's Q value for the radicalic carbon atom in noted and discussed. © 1969, Walter de Gruyter. All rights reserved.

引用

页码：279 / &

共 26 条

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