FIXATION OF THE TERTIARY GROUP GEM-DIMETHYLPROPYNYL HCCC(CH3)2 WITH ORGANOMETAL COMPOUND - APPLICATIONS

被引：6

作者：

BARBOT, F ^{[1
]}

MIGINIAC, P ^{[1
]}

机构：

[1] UNIV POITIERS,CHIM ORGANOMET LAB,CNRS,UA 574,40 AVE RECTEUR PINEAU,F-86022 POITIERS,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 440卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)80204-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Organometallics (CH3)2C=C=CHM (M = MgBr, Al2/3Br, ZnBr) are easily prepared from the tertiary bromide (CH3)2C(Br)C=CH. They often react to give only acetylenic products but, with some reagents, a mixture of acetylenic and allenic compounds is obtained.

引用

页码：249 / 261

页数：13

共 42 条

[1]

BARBOT F, 1984, B SOC CHIM FR II-CH, P83

[2]

BARBOT F, 1981, J CHEM RES-S, P343

[3] REACTION OF ALPHA-UNSATURATED ORGANOALUMINUM COMPOUNDS WITH ACETALS AND KETALS [J].

BARBOT, F ;

MIGINIAC, P .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 170 (01) :1-8

[4]

BARBOT F, 1983, SYNTHESIS-STUTTGART, P651

[5]

BARBOT F, 1981, J CHEM RES M, P4016

[6] A SIMPLE, NEW PREPARATION OF ALPHA, ALPHA-DIMETHYLALLYLTRIMETHYLSILANE - A USEFUL PRENYLATION REAGENT [J].

BENNETAU, B ;

PILLOT, JP ;

DUNOGUES, J ;

CALAS, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (21) :1094-1095

[7] N,N-BIS(TRIMETHYLSILYL)AMINOMETHYLATION OF GRIGNARD COMPOUNDS - A VERSATILE AMINE SYNTHESIS [J].

BESTMANN, HJ ;

WOLFEL, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (01) :53-53

[8]

BESTMANN HJ, 1987, SYNTHESIS-STUTTGART, P848

[9]

BRANDSMA L, 1988, PREPARATIVE ACETYLEN, P249

[10]

BRANDSMA L, 1971, PREPARATIVE ACETYLEN, P135

← 1 2 3 4 5 →