FIXATION OF THE TERTIARY GROUP GEM-DIMETHYLPROPYNYL HCCC(CH3)2 WITH ORGANOMETAL COMPOUND - APPLICATIONS

被引：6

作者：

BARBOT, F ^{[1
]}

MIGINIAC, P ^{[1
]}

机构：

[1] UNIV POITIERS,CHIM ORGANOMET LAB,CNRS,UA 574,40 AVE RECTEUR PINEAU,F-86022 POITIERS,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 440卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)80204-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Organometallics (CH3)2C=C=CHM (M = MgBr, Al2/3Br, ZnBr) are easily prepared from the tertiary bromide (CH3)2C(Br)C=CH. They often react to give only acetylenic products but, with some reagents, a mixture of acetylenic and allenic compounds is obtained.

引用

页码：249 / 261

页数：13

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