PHOTOELECTRON-SPECTRA OF THE GAUCHE-CONFORMERS AND TRANS-CONFORMERS OF 1,2-BROMOCHLOROETHANE

被引:9
作者
CARNOVALE, F [1 ]
GAN, TH [1 ]
PEEL, JB [1 ]
机构
[1] LA TROBE UNIV,ELECTRON MICROSCOPY RES INST,BUNDOORA 3083,VICTORIA,AUSTRALIA
关键词
D O I
10.1016/0368-2048(79)85007-0
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The HeI photoelectron spectra of the gauche and trans conformers of 1,2-bromochloroethane have been obtained by analysis of time-averaged spectra recorded at different temperatures. Variations in ionization potentials of the two conformers are consistent with data obtained from molecular orbital calculations. Analysis of a HEII spectrum and comparisons with the related molecules 1,2-dichloroethane and 1,2-dibromoethane shows that the ClBr non-bonded interactions include both through-bond and through-space contributions. © 1979.
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页码:87 / 96
页数:10
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