PHOTOELECTRON-SPECTRA OF THE GAUCHE-CONFORMERS AND TRANS-CONFORMERS OF 1,2-BROMOCHLOROETHANE

被引：9

作者：

CARNOVALE, F ^{[1
]}

GAN, TH ^{[1
]}

PEEL, JB ^{[1
]}

机构：

[1] LA TROBE UNIV,ELECTRON MICROSCOPY RES INST,BUNDOORA 3083,VICTORIA,AUSTRALIA

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1979年 / 16卷 / 1-2期

关键词：

D O I：

10.1016/0368-2048(79)85007-0

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The HeI photoelectron spectra of the gauche and trans conformers of 1,2-bromochloroethane have been obtained by analysis of time-averaged spectra recorded at different temperatures. Variations in ionization potentials of the two conformers are consistent with data obtained from molecular orbital calculations. Analysis of a HEII spectrum and comparisons with the related molecules 1,2-dichloroethane and 1,2-dibromoethane shows that the ClBr non-bonded interactions include both through-bond and through-space contributions. © 1979.

引用

页码：87 / 96

页数：10