SURFACE-INDUCED DISSOCIATION IN TANDEM QUADRUPOLE MASS SPECTROMETERS - A COMPARISON OF 3 DESIGNS

被引：101

作者：

WYSOCKI, VH ^{[1
]}

DING, JM ^{[1
]}

JONES, JL ^{[1
]}

CALLAHAN, JH ^{[1
]}

KING, FL ^{[1
]}

机构：

[1] USN,RES LAB,DIV CHEM,WASHINGTON,DC 20375

来源：

JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY | 1992年 / 3卷 / 01期

关键词：

D O I：

10.1016/1044-0305(92)85015-C

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Three different devices that can be used for surface-induced dissociation (SID) in tandem quadrupole instruments are compared here. The designs were compared by examining the fragmentation of several compounds including benzene, W(CO)6, and (CH3)4N+. These studies show that SID can be readily implemented on a variety of tandem quadrupole instruments and that the spectra obtained with the in-line and 90-degrees instruments are similar. Evidence is presented that confirms that high average internal energies and narrow distributions of internal energy are available by this technique. Efficiencies for fragmentation of odd-electron ions are on the order of those previously reported by others. The overall SID efficiency for even-electron ions is higher than that for odd-electron ions of similar structure.

引用

页码：27 / 32

页数：6

共 16 条

[1] MICROCHANNEL PLATE FOR SURFACE-INDUCED DISSOCIATION IN MASS-SPECTROMETRY
ABERTH, W
[J]. ANALYTICAL CHEMISTRY, 1990, 62 (06) : 609 - 611
[2] ALCORN RL, SECONDARY ION MASS S, V6, P153
[3] REACTIVE COLLISIONS OF POLYATOMIC IONS AT SOLID-SURFACES
AST, T
MABUD, MA
COOKS, RG
[J]. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 1988, 82 (1-2) : 131 - 150
[4] TANDEM MASS-SPECTROMETRY USING AN IN-LINE ION SURFACE COLLISION DEVICE
BIER, ME
SCHWARTZ, JC
SCHEY, KL
COOKS, RG
[J]. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1990, 103 (01): : 1 - 19
[5] Busch KL., 1988, MASS SPECTROMETRY MA
[6] DETERMINATION AND ENHANCEMENT OF STEREOSPECIFIC DECOMPOSITIONS VIA TRIPLE MASS-SPECTROMETRY - FORMATION OF UNTYPICAL PROTONATED PRECURSOR MOLECULES
COLE, RB
TABET, JC
[J]. ORGANIC MASS SPECTROMETRY, 1991, 26 (02): : 59 - 66
[7] COLLISIONS OF POLYATOMIC IONS WITH SURFACES
COOKS, RG
AST, T
MABUD, A
[J]. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 1990, 100 : 209 - 265
[8] ENERGY DEPOSITION IN [FE(CO)5]+. UPON COLLISION WITH A METAL-SURFACE
DEKREY, MJ
KENTTAMAA, HI
WYSOCKI, VH
COOKS, RG
[J]. ORGANIC MASS SPECTROMETRY, 1986, 21 (04): : 193 - 195
[9] ION SURFACE COLLISIONS FOR DISTINCTION OF ISOMERIC [C6H6].+ AND [C6H6]2+ IONS
HAYWARD, MJ
MABUD, MA
COOKS, RG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (05) : 1343 - 1346
[10] SURFACE-INDUCED DISSOCIATION BY FOURIER-TRANSFORM MASS-SPECTROMETRY
IJAMES, CF
WILKINS, CL
[J]. ANALYTICAL CHEMISTRY, 1990, 62 (13) : 1295 - 1299

← 1 2 →