PHOTOCHEMISTRY OF (ME3P)4MO(ETA-2-CO2)2 - DEOXYGENATION OF COORDINATED CARBON-DIOXIDE AND PHOSPHINE OXIDATION

被引：14

作者：

ZIEGLER, W ^{[1
]}

NICHOLAS, KM ^{[1
]}

机构：

[1] UNIV OKLAHOMA,DEPT CHEM & BIOCHEM,NORMAN,OK 73019

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 423卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)83136-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Irradiation of the title compound 1 through quartz in toluene solution at -20-degrees-C produces cis-Mo(CO)2(PMe3)4 and OPMe3 as the major products along with lesser amounts of mer- and fac-Mo(CO)3(PMe3)3 and Mo(CO)(PMe3)5. Irradiation of 1 through Pyrex produces in addition substantial amounts of an unstable species formulated as trans-Mo(CO)2(PMe3)4.

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页码：C35 / C37

页数：3

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