CHEMISTRY OF CYANOACETYLENES .2. CYANOENAMINES THEIR PREPARATION AND REACTIONS

被引：24

作者：

SASAKI, T

YOSHIOKA, T

SHOJI, K

机构：

[1] Institute of Applied Organic Chemistry, Faculty of Engineering, Nagoya University, Chikusa-ku, Nagoya

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 07期

关键词：

D O I：

10.1039/j39690001086

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cyanoenamines were prepared by addition of cyclic secondary amines to cyanoacetylene. Acidic hydrolysis of 3-morpholinoacrylonitrile afforded formylacetic acid. Treatment of the same cyanoenamine with acyl chlorides gave, unexpectedly, 4-morpholinobutadiene-1,3-dicarbonitrile. Reactions of 3-aziridin-1-ylacrylonitrile with p-nitrobenzoic acid, sodium iodide in acetone, and sodium iodide in carbon disulphide afforded 2-(2-cyanovinylamino)ethyl p-nitrobenzoate, 3-(2,2-dimethyl-1,3-oxazolidin-1-yl)acrylonitrile, and 3-(2-thioxo-1,3-thiazolidin-1-yl)acrylonitrile, respectively.

引用

页码：1086 / &

共 14 条

[1]

ALT CH, 1964, J ORG CHEM, V29, P789

[2]

CAMPBELL RD, 1964, J ORG CHEM, V29, P3711

[3] HETEROCYCLIZATION OF EPIMERIC AMINOCYCLANOLS .1. OXAZOLINES [J].