DOUBLE DEPROTONATION, RING-OPENING AND C-C BOND FORMATION IN A COORDINATED CROWN THIOETHER - FORMATION AND STRUCTURE OF AN ARENERUTHENIUM(II) ETHENETHIOLATE, [RU(SCH=CH2)(ETA-6-C6ME5CH2CH2CH2SCH2CH2S)]

被引：41

作者：

BENNETT, MA

GOH, LY

WILLIS, AC

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 17期

关键词：

D O I：

10.1039/c39920001180

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of [Ru(eta-6-C6Me6)([9]aneS3)](PF6)2 ([9]aneS3 = 1,4,7-trithiacyclononane) with an excess of potassium tert-butoxide gives an eta-1-S-bonded ethenethiolate complex, [Ru(SCH=CH2)(eta-6-C6Me5CH2CH2CH2SCH2CH2S)], which is characterised by single crystal X-ray analysis; it is formed as a result of deprotonation at two of the methylene carbon atoms of [9]aneS3 and cleavage of two C-S bonds, followed by deprotonation at one of the C6Me6 methyl groups.

引用

页码：1180 / 1182

页数：3

共 19 条

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